A picture of placidity (5)
I believe the answer is:
still
'a picture' is the definition.
(still is a kind of picture)
I don't understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for still that I've seen before include "Silence" , "Tranquil" , "source of spirits" , "Immobile" , "Not going anywhere" .)