Chap touring a film centre in Italy (5)
I believe the answer is:
milan
'in italy' is the definition.
('Milan' is part of 'italy')
'chap touring a film centre' is the wordplay.
'chap' becomes 'man' (chap can mean a man).
'touring' means one lot of letters goes inside another (touring can mean going round).
'centre' says to take the centre.
The centre of 'film' is 'il'.
'man' placed around 'il' is 'MILAN'.
(Other definitions for milan that I've seen before include "North Italian city" , "town" , "Doorstep deliverer" , "European city" , "Italian industrial city" .)