Each woman going to extremes of roguery (5)
I believe the answer is:
every
'each' is the definition.
(synonyms)
'woman going to extremes of roguery' is the wordplay.
'woman' becomes 'eve' (Eve is an example).
'going to' says to put letters next to each other.
'extremes of' says to hollow out the word (remove centre letters) (only the letters at the extremes of the word).
'roguery' with its middle removed is 'ry'.
'eve'+'ry'='EVERY'
(Other definitions for every that I've seen before include "Each of a number" , "All, taken separately" , "'God bless us - - one !'" , "Each (one of a set)" , "As much as possible" .)