Snake in devilish guise (7)
I believe the answer is:
serpent
'snake' is the definition.
(synonyms)
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for serpent that I've seen before include "Early wind instrument" , "Limbless reptile" , "Large snake, dragon" , "Fruit supplier" , "Snake - old wind instrument" .)