The smoke, perhaps, but not London (6)
I believe the answer is:
havana
'the smoke' is the definition.
(I've seen this in another clue)
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for havana that I've seen before include "Capital of Cuba" , "Smoke" , "island capital" , "Caribbean capital" , "city" .)