A London orchestra too! (4)
I believe the answer is:
also
'too' is the definition.
(synonyms)
'a london orchestra' is the wordplay.
'london orchestra' becomes 'LSO' (london symphony orchestra).
'a'+'lso'='ALSO'
(Other definitions for also that I've seen before include "What's more" , "item's rarely used now for this" , "Item" , "in accompaniment" , "To boot" .)