Love to work with one fabric (5)
I believe the answer is:
voile
'fabric' is the definition.
(voile is a kind of fabric)
'love to work with one' is the wordplay.
'to work with' indicates anagramming the letters.
'one' becomes 'i' (Roman numeral).
'love' mixed up with 'i' can make 'VOILE'.
(Other definitions for voile that I've seen before include "fine material" , "Sheer fabric" , "Light semi-transparent fabric" .)