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Painting fine Scilly isle, but not the capital (6)


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'painting' is the definition.
(I know that fresco is a type of painting)

I don't understand how the remainder of the clue works.

Can you help me to learn more?

(Other definitions for fresco that I've seen before include "Painting done in wet plaster" , "Mural painting" , "Forces (anag) - wall painting" , "Artistic work" , "Mural painted on wet plaster" .)

I've seen this clue in The Times.
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