Sunny little chap? (3)
I believe the answer is:
sol
'chap' is the definition.
'sunny little' is the wordplay.
'sunny' becomes 'so' (I am not sure about this - if you are sure you should believe this answer much more).
'little' becomes 'L' (abbreviation for little).
'so'+'l'='SOL'
Can you help me to learn more?
(Other definitions for sol that I've seen before include "Note; Peruvian currency" , "Fifth note of scale" , "The sun in Spain" , "A Latin sun" , "The sun in 12 Across" .)