Tip over or spill (5)

I believe the answer is:

upset

I believe this is a double definition.

'tip over' is the first definition.
(synonyms)

'spill' is the second definition.
(I've seen this before)

(Other definitions for upset that I've seen before include "Disturb(ance)" , "Perturbed - unexpected defeat" , "Disconcerted, discomposed" , "Unexpected defeat - tipped over" , "Capsize" .)

I've seen this clue in The Mirror.

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