Long ones wont be associated with favourites (4)
I believe the answer is:
odds
'long ones' is the definition.
The definition suggests a plural noun which matches the answer.
I don't understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for odds that I've seen before include "Betting ratio" , "Scraps" , "Betting figures" , "Probabilities" , "Betting price" .)