A diatribe from one in commerce (6)
I believe the answer is:
tirade
'a diatribe' is the definition.
(I've seen this before)
'one in commerce' is the wordplay.
'one' becomes 'i' (Roman numeral).
'in' is an insertion indicator.
'commerce' becomes 'trade' (trade is a kind of commerce).
'i' inserted within 'trade' is 'TIRADE'.
'from' acts as a link.
(Other definitions for tirade that I've seen before include "Verbal broadside" , "A long, abusive outburst" , "Fulmination" , "Stream of invective" , "Long angry harangue" .)