Disconcerted, ashamed (7)
I believe the answer is:
abashed
This clue is a double definition.
'disconcerted' is the first definition.
(abashing is a kind of disconcerting)
'ashamed' is the second definition.
(thesaurus)
(Other definitions for abashed that I've seen before include "Embarrassed or disconcerted" , "Disturbed" , "Confounded" , "Embarrassed or ashamed" , "Shamefaced" .)