Flavouring ingredient essential to vegan's barley slices (6)
I believe the answer is:
garlic
'flavouring' is the definition.
(I know that garlic is a type of flavouring)
I can't explain the remainder of the clue.
Can you help me to learn more?
(Other definitions for garlic that I've seen before include "Bulb used in cooking" , "Pungent bulbs" , "Aioli ingredient" , "something with strong smell" , "Bulb used in cookery" .)