Good-looking and generous (8)
I believe the answer is:
handsome
I believe this clue is a double definition.
'good-looking' is the first definition.
(synonyms)
'generous' is the second definition.
(similar in meaning)
'and' acts as a link.
(Other definitions for handsome that I've seen before include "Pleasing to see" , "Pleasing in appearance" , "Fit" , "beautiful" , "Fine-looking" .)