Headland; garment (4)
I believe the answer is:
cape
I believe this is a double definition.
'headland' is the first definition.
(I've seen this before)
'garment' is the second definition.
(cape is a kind of garment)
(Other definitions for cape that I've seen before include "Cloak; head" , "Wrath, say" , "Batman has one" , "Wrath perhaps" , "Cod possibly" .)