Like buccaneer briefly left below island hoping to make it (12)
I believe the answer is:
aspirational
'hoping to make it' is the definition.
(having aspirations to make it in life)
'like buccaneer briefly left below' is the wordplay.
'like' becomes 'as'.
'buccaneer' becomes 'pirate' (historical term for a pirate).
'briefly' means to remove the last letter.
'left below' becomes 'ional' (I can't explain this - if you can you should give a lot more credence to this answer).
'pirate' with its final letter removed is 'pirat'.
'as'+'pirat'+'ional'='ASPIRATIONAL'
'island' is the link.
This may not be correct. It may belong to another bit of the clue.
(Other definitions for aspirational that I've seen before include "After a role model" , "Characterised by a desire to be successful" , "Like those trying to succeed" , "Characterised by hope or ambition" , "Pertaining to hopes" .)