Make-up and paint intended for audience (11)
I believe the answer is:
temperament
'make-up' is the definition.
'paint intended for audience' is the wordplay.
'paint' becomes 'tempera' (tempera is a kind of paint).
'intended' becomes 'meant' (meaning is a kind of intending).
'for audience' indicates a 'sounds like' (homophone) clue.
'meant' is a homophone of 'ment'.
'tempera'+'ment'='TEMPERAMENT'
'and' is the link.
(Other definitions for temperament that I've seen before include "A person's nature as it affects behaviour" , "Frame of mind" , "Piano tuning; character" , "Person's nature; adjustment in piano tuning" , "Personality" .)