Mesmerise commander at centre, displaying fish-like creature (6)
I believe the answer is:
merman
'fish-like creature' is the definition.
I can't tell whether this defines the answer.
'mesmerise commander at centre' is the wordplay.
'mesmerise' becomes 'mer' (I am not sure about this - if you are sure you should give a lot more credence to this answer).
'at centre' indicates the central letters.
The central letters of 'commander' are 'man'.
'mer'+'man'='MERMAN'
'displaying' acts as a link.
Can you help me to learn more?
(Other definitions for merman that I've seen before include "fishy character" , "Fabulous creature" , "Half man, half fish" , "Ethel --, singer" .)