Ned leaves on the dot with canine (5)
I believe the answer is:
tooth
'canine' is the definition.
(thesaurus)
I don't understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for tooth that I've seen before include "Gearwheel projection" , "Let it stand" , "Jag on the edge of a saw" , "Projection of a gear wheel" , "Bonelike structure" .)