Toledo sadly got plundered (6)
I believe the answer is:
looted
'plundered' is the definition.
(synonyms)
'toledo sadly' is the wordplay.
'sadly' is an anagram indicator.
'toledo' anagrammed gives 'LOOTED'.
'got' is the link.
(Other definitions for looted that I've seen before include "having taken part in a robbery" , "Sacked" , "Plundered and robbed" , "Plundered, pillaged" , "stole stuff" .)